2-(4-Chlorophenyl)-3,5-dimethyl-1λ6,2-thiazine-1,1-dione
نویسندگان
چکیده
In the title compound, C(12)H(12)ClNO(2)S, the S atom is displaced by 0.708 (2) Å out of the plane through the remaining atoms of the thia-zine ring (r.m.s. deviation = 0.0823 Å). This plane makes a dihedral angle of 89.33 (7)° with the phenyl ring. In the crystal, adjacent mol-ecules are connected through C-H⋯O hydrogen bonds into layers parallel to the bc plane.
منابع مشابه
2-[2-(3-Chlorophenyl)-2-oxoethyl]-4-hydroxy-3-(3-methoxybenzoyl)-2H-1λ6,2-benzothiazine-1,1-dione
In the title mol-ecule, C(24)H(18)ClNO(6)S, the heterocyclic thia-zine ring adopts a half chair conformation with the S and N atoms displaced by 0.318 (3) and 0.387 (3) Å, respectively, on the opposite sides from the mean plane formed by the remaining ring atoms. The benzene rings of the benzothia-zin unit and meth-oxy-benzoyl group are more or less coplanar, the dihedral angle between the mean...
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In the title compound, [Pt(C17H19N4)Cl], the Pt(II) cation is C,C',C''-chelated by the 1,1'-(5-methyl-1,3-phenyl-ene)bis-(3,5-dimethyl-1H-imidazolyl-idene) anion and coordinated by a Cl(-) anion in a distorted square-planar coordination geometry. π-π stacking is observed between nearly parallel imidazole and benzene rings of adjacent mol-ecules, the centroid-centroid distance being 3.802 (4) Å.
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عنوان ژورنال:
دوره 67 شماره
صفحات -
تاریخ انتشار 2011